2-(4-Chlorophenyl)acetamide
نویسندگان
چکیده
In the title compound, C(8)H(8)ClNO, the acetamide group is twisted out the benzene plane with a dihedral angle of 83.08 (1)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming layers parallel to the ab plane.
منابع مشابه
Crystal structures of two C,N-disubstituted acetamides: 2-(4-chlorophenyl)-N-(2-iodophenyl)acetamide and 2-(4-chlorophenyl)-N-(pyrazin-2-yl)acetamide
In the crystal of 2-(4-chloro-phen-yl)-N-(2-iodo-phen-yl)acetamide, C14H11ClINO, mol-ecules are linked by a combination of N-H⋯O and C-H⋯O hydrogen bonds to form a C(4)C(4)[R21(7)] chain of rings and chains of this type are linked by a combination of C-Cl⋯π(arene) and C-I⋯π(arene) inter-actions to form deeply puckered twofold inter-woven sheets. In the crystal of 2-(4-chloro-phen-yl)-N-(pyrazin...
متن کاملN-(4-Chlorophenyl)-2-(hydroxyimino)acetamide
The title compound, C(8)H(7)ClN(2)O(2), is an inter-mediate in the synthesis of 5-chloro-isatin, which can be further transformed to 5-chloro-2-indolinone via a Wolff-Kishne reduction. The C(2)N acetamide plane forms a dihedral angle of 6.3 (3)° with the benzene ring. An intra-molecular C-H⋯O inter-action results in the formation of a six-membered ring. In the crystal, inter-molecular N-H⋯O, N-...
متن کامل2-(4-Chlorophenyl)-N-(3,4-difluorophenyl)acetamide
In the title compound, C14H10ClF2NO, the dihedral angle between the mean planes of the 4-chloro-phenyl and 3,4-di-fluoro-phenyl rings is 65.2 (1)°. These two planes are twisted by 83.5 (5) and 38.9 (9)°, respectively, from that of the acetamide group. In the crystal, N-H⋯O hydrogen bonds form infinite chains along [100]. Weak C-H⋯O and C-H⋯F inter-actions are also observed and stack mol-ecules ...
متن کاملN-(4-Chlorophenyl)-2-(8-quinolyloxy)acetamide monohydrate
In the title compound, C(17)H(13)ClN(2)O(2)·H(2)O, the dihedral angle between the quinoline ring system and the benzene ring is 13.0 (1)°. An intra-molecular N-H⋯O hydrogen bond may influence the mol-ecular conformation. In the crystal structure, acetamide mol-ecules are linked to water mol-ecules via inter-molecular O-H⋯ N and N-H⋯O hydrogen bonds and in turn linked into chains along [010] via...
متن کامل4-(4-Chlorophenyl)-5-(4-nitrophenyl)-3-phenyl-4H-1,2,4-triazole
The title compound, C(20)H(13)ClN(4)O(2), was synthesized by the condensation of 4-nitro-benzohydrazide and N-(4-chlorophen-yl)-benzimidoyl chloride in N,N-dimethyl-acetamide. The asymmetric unit contains two independent mol-ecules. In one molecule, the triazole ring is oriented at dihedral angles of 23.1 (5), 85.4 (1) and 10.5 (1)° with respect to the phenyl, chlorophenyl and nitrophenyl rings...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011